物理描述 Physical Description
Propargyl alcohol appears as a clear colorless liquid with a geranium-like odor. Flash point 97°F. Vapors are heavier than air. Used to make other chemicals, as a corrosion inhibitor and a soil fumigant.
颜色/状态 Color Form
Colorless liquid
气味 Odor
Mild, geranium odor
沸点 Boiling Point
113.6 °C
熔点 Melting Point
-51.8 °C
闪点 Flash Point
33 °C c.c.
溶解度 Solubility
Miscible (NIOSH, 2016)
密度 Density
0.9715 at 20 °C/4 °C
蒸气密度 Vapor Density
Relative vapor density (air = 1): 1.93
蒸汽压力 Vapor Pressure
15.6 mm Hg at 25 °C
粘度 Viscosity
1.68 centipoise at 20 °C
电离电位 Ionization Potential
10.51 eV
气味阈值 Odor Threshold
0.35 mg/cu m
折光率 Refractive Index
Index of refraction: 1.43064 at 20 °C/D
保留指数 Kovats Retention Index
559;546;552;559;576;552;559;569;576;566;552.5;565.8;549.6;546
其他实验性质 Other Experimental Properties
Henry's Law constant = 1.2X10-6 atm-cu m/mol at 25 °C (est)
聚合 Polymerization
May polymerize explosively. Polymerization may be caused by elevated temperature, oxidizers, peroxides, caustic solutions, or sunlight. Uninhibited monomer vapor may form polymer in vents and other confined spaces.
辛醇/水分配系数 LogP
-0.38 (LogP)
辛醇/水分配系数 LogP
-0.4
重原子数 Heavy atoms count
4
可旋转键数 Rotatable bond count
0
环数 Number of rings
0
sp3杂化的碳原子比例 Carbon bond saturation (Fsp3)
0.333
拓扑面积 Polar surface area (Å)
20.2
氢给体数 Hydrogen bond donors count
1
氢受体数 Hydrogen bond acceptors count
1
Propargyl alcohol is quickly distributed and excreted following an iv dose. The majority of the radioactivity ((14)C-labeled test material) was excreted in the urine and as carbon dioxide in the breath of both rats and mice. Oral dosing resulted in a similar rapid (but slower than after iv dosing) excretion pattern, with the bulk of radioactivity being excreted in the urine and exhaled carbon dioxide. Dermal absorption was low due to the volatility of propargyl alcohol. Inhalation exposure resulted in 55 to 63% absorption of inhaled propargyl alcohol at 1 or 10 ppm and only 23 to 33% absorption at 100 ppm. Both species eliminated the majority of the inhaled dose in urine.
... /Propargyl alcohol/ can be absorbed into the body by inhalation of its vapor, through the skin and by ingestion.
危险品标志
T
WGK Germany
2
危险品运输编号
UN 2929 6.1/PG 1
海关编码
2905290000
RTECS号
UK5075000
包装等级
II
危险类别
6