三氯化铁 iron(III) chloride

概况

三氯化铁化学式
  • 中文名称

  • 英文名称

    iron(III) chloride; anhydrous ferric chloride; ferric(III) chloride; iron (III) chloride; ferric trichloride; iron(II) chloride; iron trichloride

  • 化学式

    Cl3Fe

  • 分子量

    162.2

  • 分类属性

    开链化合物氯代烃

  • 类药性

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编码系统

物化性质

  • 物理描述 Physical Description

    Ferric chloride is an orange to brown-black solid. It is slightly soluble in water. It is noncombustible. When wet it is corrosive to aluminum and most metals. Pick up and remove spilled solid before adding water. It is used to treat sewage, industrial waste, to purify water, as an etching agent for engraving circuit boards, and in the manufacture of other chemicals.

  • 颜色/状态 Color Form

    Hexagonal red by transmitted light, green by reflected light; sometimes appears brownish-black; dark leaflets or plates.

  • 沸点 Boiling Point

    About 316 °C

  • 熔点 Melting Point

    304 °C

  • 溶解度 Solubility

    430 g/kg solution at 0 °C; 480 g/kg solution at 20 °C; 743 g/kg solution at 40 °C

  • 密度 Density

    2.90 at 25 °C

  • 蒸汽压力 Vapor Pressure

    Vapor pressure at 20 °C: negligible

  • 分解 Decomposition

    When heated to decomposition it emits highly toxic fumes of /hydrogen chloride/.

  • 腐蚀性 Corrosivity

    Water solutions are acidic and corrosive to most metals.

  • 其他实验性质 Other Experimental Properties

    VP: 1 Pa at 118 °C; 100 Pa at 190 °C; 100 kPa at 319 °C

计算性质

  • 辛醇/水分配系数 LogP

    2.07

  • 重原子数 Heavy atoms count

    4

  • 可旋转键数 Rotatable bond count

    0

  • 环数 Number of rings

    0

  • sp3杂化的碳原子比例 Carbon bond saturation (Fsp3)

    0

  • 拓扑面积 Polar surface area (Å)

    0

  • 氢给体数 Hydrogen bond donors count

    0

  • 氢受体数 Hydrogen bond acceptors count

    0

分类

ADME

吸收、分配和排泄
吸收、分配和排泄

An ovine model of maternal iron poisoning in pregnancy was used to examine the placental transport of deferoxamine and ferrioxasmine and to follow maternal and fetal serum iron concentrations when maternal serum iron levels exceeded total iron-binding capacity. Ewes in the third stage of gestation underwent hysterectomy and delivery of the fetal head through an abdominal incision while under ketamine and halothane anesthesia. The fetal external jugular vein was catheterized for sampling of venous blood while the fetus remained in utero. Administration of deferoxamine mesylate or ferrioxamine mesylate IV to ewes was not accompanied by measurable deferoxamine or ferrioxamine in fetal blood. In a final experiment, four gravid ewes in a control group received 2 mg/kg maternal body wt iron IV over 60 minutes. An experimental group comprision another four ewes received similar doses of iron but then received 50 mg/kg deferoxamine mesylate IV over 15 minutes. Control and deferoxamine ewes reached similar peak maternal serum iron concentration (2,479 + or - 266 and 2,121 + or - 343 ug/dL, respectively). The markedly elevated maternal serum iron concentrations were not accompanied by meaningful elevations in fetal serum iron level over baseline values. Maternal deferoxamine infusion resulted in a more rapid fall in maternal serum iron concentrations but had no effect on fetal serum iron levels. The ovine fetus appears to be protected from elevated maternal serum iron concentrations in the last trimester of prenancy. It could not be demonstrated that meaningful quantities of deferoxamine or ferrioxamine cross the placenta in the last trimester.

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晶体信息

安全信息

  • 危险品标志

    Xn

  • WGK Germany

    1

  • 危险品运输编号

    UN 1773

  • 海关编码

    2827399000

  • 危险标志

    GHS02;GHS05;GHS07

  • RTECS号

    LJ9100000

  • 包装等级

    III

  • 危险类别

    8

  • 安全说明
    S26;S39
  • 危险类别码
    R22;R41;R38
  • 危险性描述
    H226;H290;H315;H318;H335
  • 危险性防范说明
    P261;P280;P305 + P351 + P338

SDS

提供商 修订日期 查看
COMBI-BLOCKS 2019-12-13 点击查看
Science Lab 2013-05-21 点击查看
Aldrich 2022-02-22 点击查看
Sigma Aldrich 2022-02-22 点击查看
POCH 2005-08-24 点击查看
Aldrich 2016-05-27 点击查看
POCH 2005-08-24 点击查看
POCH 2005-08-24 点击查看
POCH 2005-08-24 点击查看
POCH 2005-08-24 点击查看
Alfa Aesar 2018-03-02 点击查看
Strem Chemicals, Inc 2016-07-31 点击查看
Fisher Scientific Company 点击查看
Fisher Scientific Company 点击查看
Fisher Scientific Company 点击查看