三氯化铝 aluminium trichloride

概况

三氯化铝化学式
  • 中文名称

  • 英文名称

    aluminium trichloride; aluminium chloride anhydrous; aluminium(III) chloride; aluminum(III) chloride; aluminum trichloride; aluminium chloride; aluminum chloride

  • 化学式

    AlCl3

  • 分子量

    133.34

  • 分类属性

    开链化合物氯代烃

  • 类药性

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编码系统

物化性质

  • 物理描述 Physical Description

    Aluminum chloride, anhydrous appears as a white to gray powder with a pungent odor. Corrosive to tissue and toxic by ingestion.

  • 颜色/状态 Color Form

    White when pure; ordinarily gray or yellow to greenish

  • 气味 Odor

    STRONG ODOR OF HYDROGEN CHLORIDE

  • 沸点 Boiling Point

    182.7 °C at 752 mm Hg /Sublimation temperature/

  • 熔点 Melting Point

    192.6 °C

  • 溶解度 Solubility

    Water reactive

  • 密度 Density

    2.44 at 77 °F (USCG, 1999)

  • 蒸汽压力 Vapor Pressure

    1 mm Hg at 100.0 °C

  • 稳定性/保质期 Stability Shelf Life

    Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/

  • 自燃温度 Autoignition Temperature

    Not flammable (USCG, 1999)

  • 气味阈值 Odor Threshold

    Gives water a bitter astringent taste, with perception threshold at a concentration of 0.1 mg/L; odor perception threshold is 0.5 mg/L (calculating on the aluminum ion).

  • 其他实验性质 Other Experimental Properties

    VAP: 1 Pa at 58.4 °C; 10 Pa at 76.5 °C; 100 Pa at 97.1 °C; 1 kPa at 120.7 °C; 10 kPa at 148.2 °C; 100 kPa at 180.5 °C (solid at each temp)

计算性质

  • 辛醇/水分配系数 LogP

    1.69

  • 重原子数 Heavy atoms count

    4

  • 可旋转键数 Rotatable bond count

    0

  • 环数 Number of rings

    0

  • sp3杂化的碳原子比例 Carbon bond saturation (Fsp3)

    0

  • 拓扑面积 Polar surface area (Å)

    0

  • 氢给体数 Hydrogen bond donors count

    0

  • 氢受体数 Hydrogen bond acceptors count

    0

分类

ADME

吸收、分配和排泄
代谢
吸收、分配和排泄

It is reported that about 17-30 % of aluminum chloride formed from the reaction between orally ingested aluminum hydroxide and hydrochloric acid of the stomach is absorbed [L2013]. In rabbits, administration of a single maximum safe oral dose aluminum chloride (333 mg Al/kg) resulted in aluminum absorption of 0.57 % [L2013]. Aluminum chloride may be absorbed via dermal route, with the uptake increasing in the microgram range but with an upper limit [L2013].

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代谢

Absorbed aluminum chloride is rapidly excreted by the kidneys in individuals with normal renal function [L2013]. Aluminum chloride may be absorbed dermally.

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晶体信息

安全信息

  • 危险品标志

    C;T;Xi

  • WGK Germany

    1

  • 危险品运输编号

    UN 3264

  • 海关编码

    2827320000

  • 危险标志

    GHS05;GHS06;GHS08

  • RTECS号

    BD0525000

  • 包装等级

    II

  • 安全说明
    S45;S28
  • 危险类别码
    R34
  • 危险性描述
    H301 + H311 + H331;H314;H351;H360F;H372;H412
  • 危险性防范说明
    P201;P280;P303 + P361 + P353;P304 + P340 + P310;P305 + P351 + P338;P308 + P313

SDS

提供商 修订日期 查看
Acros Organics 2014-07-23 点击查看
EMD Millipore 2018-09-18 点击查看
POCH 2005-06-30 点击查看
BASF 2014-07-28 点击查看
EMD Millipore 2018-09-18 点击查看
BASF 2014-07-28 点击查看
POCH 2005-06-30 点击查看
Alfa Aesar 2018-07-06 点击查看
American Elements 2018-03-23 点击查看
Sigma Aldrich 2022-04-19 点击查看
ThermoFisher 2020-02-14 点击查看
Strem Chemicals, Inc 2016-07-29 点击查看
Strem Chemicals, Inc 2016-07-31 点击查看
Alfa Aesar 2018-07-06 点击查看
Science Lab 2013-05-21 点击查看
Strem Chemicals, Inc 2017-07-20 点击查看
Fisher Scientific Company 点击查看
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